In this paper we show that a smooth toric variety of Picard number $r\leq 3$ always admits a nef primitive collection supported on a hyperplane admitting non-trivial intersection with the cone of numerically effective divisors and cutting a facet of the pseudo-effective cone , that is . In particular this means that admits non-trivial and non-big numerically effective divisors. Geometrically this guarantees the existence of a fiber type contraction morphism over a smooth toric variety of dimension and Picard number lower than those of , so giving rise to a classification of smooth and complete toric varieties with . Moreover we revise and improve results of Oda-Miyake by exhibiting an extension of the above result to projective, toric, varieties of dimension and Picard number , allowing us to classifying all these threefolds. We then improve results of Fujino-Sato, by presenting sharp (counter)examples of smooth, projective, toric varieties of any dimension and Picard number whose non-trivial nef divisors are big, that is . Producing those examples represents an important goal of computational techniques in definitely setting an open geometric problem. In particular, for , the given example turns out to be a weak Fano toric fourfold of Picard number 4.

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