For any polynomial ideal , let the minimal triangular set contained in the reduced Buchberger-Gr"obner basis of with respect to the purely lexicographical term order be called the W-characteristic set of . In this paper, we establish a strong connection between Ritt’s characteristic sets and Buchberger’s Gr"obner bases of polynomial ideals by showing that the W-characteristic set of is a Ritt characteristic set of whenever is an ascending set, and a Ritt characteristic set of can always be computed from with simple pseudo-division when is regular. We also prove that under certain variable ordering, either the W-characteristic set of is normal, or irregularity occurs for the th, but not the th, elimination ideal of for some . In the latter case, we provide explicit pseudo-divisibility relations, which lead to nontrivial factorizations of certain polynomials in the Buchberger-Gr"obner basis and thus reveal the structure of such polynomials. The pseudo-divisibility relations may be used to devise an algorithm to decompose arbitrary polynomial sets into normal triangular sets based on Buchberger-Gr"obner bases computation.

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