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We show that inflationary models with broken rotational invariance generate testable off-diagonal signatures in the correlation between the -type distortion and temperature fluctuations of the cosmic microwave background. More precisely, scenarios with a quadrupolar bispectrum asymmetry, usually generated by fluctuations of primordial vector fields, produce a nonvanishing - correlation when . Since spectral distortions are sensitive to primordial fluctuations up to very small scales, a cosmic variance limited spectral distortion experiment can detect such effects with a high signal-to-noise ratio.

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