The shifted Tietz-Wei (sTW) oscillator is as good as traditional Morse potential in simulating the atomic interaction in diatomic molecules. By using the Pekeris-type approximation to deal with the centrifugal term, we obtain the bound-state solutions of the radial Schr"odinger equation with this typical molecular model via the exact quantization rule (EQR). The energy spectrum for a set of diatomic molecules (, $NO \left(B^2\Pi_r\right)NO \left(L’^2\phi\right)NO \left(b^4\Sigma^{-}\right)ICl\left(X^1\Sigma_g^{+}\right)ICl\left(A^3\Pi_1\right)ICl\left(A’^3\Pi_2\right)$ for arbitrary values of and quantum numbers are obtained. For the sake of completeness, we study the corresponding wavefunctions using the formula method.

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