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We study a two-component asymmetric simple exclusion process (ASEP) that is equivalent to the ASEP with second-class particles. We prove self-duality with respect to a family of duality functions which are shown to arise from the reversible measures of the process and the symmetry of the generator under the quantum algebra . We construct all invariant measures in explicit form and discuss some of their properties. We also prove a sum rule for the duality functions.

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