The purpose of this paper is to study spectral properties of a family of Cayley graphs on finite commutative rings. Let be such a ring and its set of units. Let and . We define the quadratic unitary Cayley graph of , denoted by , to be the Cayley graph on the additive group of with respect to ; that is, has vertex set such that are adjacent if and only if . It is well known that any finite commutative ring can be decomposed as $R=R_1\times R_2\times\cdots\times R_sR_iM_iR_0M_0|R_0|/|M_0| \equiv 3,(\mod,4)R{R_0\times R}|R_i|/|M_i|\equiv 1,(\mod,4)1 \le i \le s$. We compute the energies and spectral moments of such quadratic unitary Cayley graphs, and determine when such a graph is hyperenergetic or Ramanujan.

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