We investigate Ag(100) thin films epitaxially grown on a Fe(100) substrate using a low-temperature scanning tunneling microscope. Fabrication of a wedge structure by evaporating Ag through a shadow mask allows us to observe systematic evolution of quantum well (QW) states for layer thicknesses varying from 3 to 16 monolayers (ML). Close inspection of differential conductance spectra and images reveal significant modulations of QW states in the lateral directions, presumably due to the local defects at the Ag/Fe interface. The area where QW states are modulated extends over ~ 5 nm. In clear contrast, near a surface atomic step, QW states exhibit negligible changes at least up to 1 nm away from the step, leaving unmixed the two sets of neighboring QW states belonging to different thicknesses. The results are discussed in terms of a simple electron wave diffraction model.

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