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SmB6 is a promising candidate for topological Kondo insulator. In this letter, we report ultrafast carrier dynamics of SmB6. Two characteristic temperatures: T1=100 K and T2= 20 K are observed. T1 corresponds to the opening of the f-d hybridization gap revealed by an abrupt disappearance of terahertz f-band plasmon oscillations. Between T1 and T2, a phonon bottleneck effect dominates the photocarrier relaxation processes. Below T2, we observe the formation of in-gap states, which are strongly affected by optically injected hot electrons and the transient electron temperature change.

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