Unstable separatrix solutions for the first and second Painlev'e transcendents are studied both numerically and analytically. For a fixed initial condition, say , there is a discrete set of initial slopes that give rise to separatrix solutions. Similarly, for a fixed initial slope, say , there is a discrete set of initial values that give rise to separatrix solutions. For Painlev'e I the large- asymptotic behavior of is and that of is , and for Painlev'e II the large- asymptotic behavior of is and that of is . The constants , , $B_{\rm II}C_{\rm II}$ are first determined numerically. Then, they are found analytically and in closed form by reducing the nonlinear equations to the linear eigenvalue problems associated with the cubic and quartic PT-symmetric Hamiltonians and .

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