We consider the Laplacian on a class of smooth domains $\Omega\subset ^{\nu}\nu\ge 2$, with attractive Robin boundary conditions: where is the outer unit normal, and study the asymptotics of its eigenvalues as well as some other spectral properties for We work with both compact domains and non-compact ones with a suitable behavior at infinity. For domains with compact boundaries and fixed , we show that where is the eigenvalue, as soon as it exists, of with and being respectively the positive Laplace-Beltrami operator and the mean curvature on . Analogous results are obtained for a class of domains with non-compact boundaries. In particular, we discuss the existence of eigenvalues in non-compact domains and the existence of spectral gaps for periodic domains. We also show that the remainder estimate can be improved under stronger regularity assumptions. The effective Hamiltonian enters the framework of semi-classical Schr"odinger operators on manifolds, and we provide the asymptotics of its eigenvalues in the limit under various geometrical assumptions. In particular, we describe several cases for which our asymptotics provides gaps between the eigenvalues of for large .

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