In this paper, we study the following two-component systems of nonlinear Schr"odinger equations \begin{equation*} \left{\aligned&\Delta u-(\lambda a(x)+a_0(x))u+\mu_1u^3+\beta v^2u=0\quad&\bbr^3,\ &\Delta v-(\lambda b(x)+b_0(x))v+\mu_2v^3+\beta u^2v=0\quad&\bbr^3,\ &u,v\in\h,\quad u,v>0\quad\bbr^3,\endaligned\right. \end{equation*} where and are parameters; are steep potentials and are sign-changing weight functions; , , and are not necessarily to be radial symmetric. By the variational method, we obtain a ground state solution and multi-bump solutions for such systems with sufficiently large. The concentration behaviors of solutions as both and are also considered. In particular, the phenomenon of phase separations is observed in the whole space . In the Hartree-Fock theory, this provides a theoretical enlightenment of phase separation in for the 2-mixtures of Bose-Einstein condensates.

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