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In this paper, based on the theory of rooted trees and B-series, we propose the concrete formulas of the substitution law for the trees of order =5. With the help of the new substitution law, we derive a B-series integrator extending the averaged vector field (AVF) method to high order. The new integrator turns out to be of order six and exactly preserves energy for Hamiltonian systems. Numerical experiments are presented to demonstrate the accuracy and the energy-preserving property of the sixth order AVF method.

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