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We consider solutions of the defocusing nonlinear Schr"odinger (NLS) equation on the half-line whose Dirichlet and Neumann boundary values become periodic for sufficiently large . We prove a theorem which, modulo certain assumptions, characterizes the pairs of periodic functions which can arise as Dirichlet and Neumann values for large in this way. The theorem also provides a constructive way of determining explicit solutions with the given periodic boundary values. Hence our approach leads to a class of new exact solutions of the defocusing NLS equation on the half-line.

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