We consider a transmission problem for the Helmholtz equation across the boundary of an extension domain. A such boundary can be Lipschitz, fractal, or of varying Hausdorff dimension for instance. We generalise the notions of layer potential and Neumann-Poincar{é} operators, and of Calder{ó}n projectors in that context. Those boundary operators allow to connect the transmission problem (on the whole space) to one-sided problems – notably, scattering problems – with Dirichlet, Neumann and Robin boundary conditions. Since an extension domain needs no specific boundary measure, the Robin (impedance) condition is not understood in a boundary L^2-type space, rather by duality on the trace space itself. We discuss the well-posedness of the impedance scattering problem in that framework and compare to the classical L^2 setting. Our analysis allows to generalise optimisation results for acoustic scattering when the obstacle is an extension domain in any dimension.

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