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The matching energy is defined as the sum of the absolute values of the zeros of the matching polynomial of a graph, which is proposed first by Gutman and Wagner [The matching energy of a graph, Discrete Appl. Math. 160 (2012) 2177–2187]. And they gave some properties and asymptotic results of the matching energy. In this paper, we characterize the trees with vertices whose complements have the maximal, second-maximal and minimal matching energy. Further, we determine the trees with a perfect matching whose complements have the second-maximal matching energy. In particular, show that the trees with edge-independence number number whose complements have the minimum matching energy for .

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