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We say that a Lie algebra is quasi-state rigid if every Ad-invariant continuous Lie quasi-state on it is the directional derivative of a homogeneous quasimorphism. Extending work of Entov and Polterovich, we show that every reductive Lie algebra, as well as the algebras , $n \geq 1$, are rigid. On the other hand, a Lie algebra which surjects onto the three-dimensional Heisenberg algebra is not rigid. For Lie algebras of dimension and for solvable Lie algebras which split over a codimension one abelian ideal, we show that this is the only obstruction to rigidity.

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