Let be a complete non-compact Riemannian manifold satisfying the doubling volume property as well as a Gaussian upper bound for the corresponding heat kernel. We study the boundedness of the Riesz transform on both Hardy spaces and Lebesgue spaces under two different conditions on the negative part of the Ricci curvature . First we prove that if is -subcritical for some $\alpha \in [0,1)d^*\Delta^{-\frac{1}{2}}1H^p_{\overrightarrow{\Delta}}(\Lambda^1T^*M)L^p(M)p\in [1,2]$. As a consequence, the Riesz transform (on functions) is bounded on for all where depends on and the constant appearing in the doubling property. Second, we prove that if for some and , then the Riesz transform is bounded on for all . In the particular case where $v(x, r) \ge C r^Dr \ge 1|R^-| \in L^{D/2 -\eta} \cap L^{D/2 + \eta}$ for some , then is bounded on for all Furthermore, we study the boundedness of the Riesz transform of Schr"odinger operators on for under conditions on and the potential . We prove both positive and negative results on the boundedness of on

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