We adapt the Newman-Penrose formalism in general relativity to the setting of three-dimensional Riemannian geometry, and prove the following results. Given a Riemannian 3-manifold without boundary and a smooth unit vector field with geodesic flow, if an integral curve of is hypersurface-orthogonal at a point, then it is so at every point along that curve. Furthermore, if is complete, hypersurface-orthogonal, and satisfies , then its divergence must be nonnegative. As an application, we show that if the Riemannian 3-manifold is closed and a unit length with geodesic flow satisfies , then cannot be hypersurface-orthogonal, thus recovering a recent result. Turning next to scalar curvature, we derive an evolution equation for the scalar curvature in terms of unit vector fields that satisfy the condition . When the scalar curvature is a nonzero constant, we show that a hypersurface-orthogonal unit vector field satisfies $R({\boldsymbol k},\cdot,\cdot,\cdot) = 0$ if and only if it is a Killing vector field.

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