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We characterize the extremal structures for mixing walks on trees that start from the most advantageous vertex. Let be a tree with stationary distribution . For a vertex , let denote the expected length of an optimal stopping rule from to . The \emph{best mixing time} for is . We show that among all trees with , the best mixing time is minimized uniquely by the star. For even , the best mixing time is maximized by the uniquely path. Surprising, for odd , the best mixing time is maximized uniquely by a path of length with a single leaf adjacent to one central vertex.

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