Universal enhancement of superconductivity in two dimensional semiconductors at low doping by electron-electron interaction

In two-dimensional multivalley semiconductors, at low doping, even a moderate electron-electron interaction enhances the response to any perturbation inducing a valley polarization. If the valley polarization is due to the electron-phonon coupling, the electron-electron interaction results in an enhancement of the superconducting critical temperature. By performing first principles calculations beyond density functional theory, we prove that this effect accounts for the unconventional doping-dependence of the superconducting transition-temperature (T${}_c$) and of the magnetic susceptibility measured in Li${}_x$ZrNCl. By finding the conditions for a maximal T${}_c$ enhancement, we show how weakly-doped two-dimensional semiconductors provide a route towards high T${}_c$ superconductivity.