The large number of mesons observed by LHCb suggests a sizable cross section for producing doubly-heavy baryons in the same experiment. Motivated by this, we estimate masses of the doubly-heavy baryons , , and , and their hyperfine partners, using a method which accurately predicts the masses of ground-state baryons with a single heavy quark. We obtain MeV, $M(\Xi_{cc}^)= 3690 \pm 12M(\Xi_{bb}) = 10162 \pm 12M(\Xi_{bb}^)= 10184 \pm 12M(\Xi_{bc}) = 6914 \pm 13M(\Xi’{bc}) = 6933 \pm 12M(\Xi{bc}^*) = 6969 \pm 14$ MeV. As a byproduct, we estimate the hyperfine splitting between and mesons to be MeV. We discuss P-wave excitations, production mechanisms, decay modes, lifetimes, and prospects for detection of the doubly heavy baryons.

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