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The symplectic structures on -Lie algebras and metric symplectic -Lie algebras are studied. For arbitrary -Lie algebra , infinite many metric symplectic -Lie algebras are constructed. It is proved that a metric -Lie algebra is a metric symplectic -Lie algebra if and only if there exists an invertible derivation such that , and is also proved that every metric symplectic -Lie algebra $(\tilde{A}, \tilde{B}, \tilde{\omega})T^*_{\theta}3$-Lie algebra . Finally, we construct a metric symplectic double extension of a metric symplectic -Lie algebra by means of a special derivation.

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