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A classification is given for factorizations of almost simple groups with at least one factor solvable, and it is then applied to characterize -arc-transitive Cayley graphs of solvable groups, leading to a striking corollary: Except the cycles, every non-bipartite connected 3-arc-transitive Cayley graph of a solvable group is a cover of the Petersen graph or the Hoffman-Singleton graph.

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