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KamLAND-PICO project aims to search for WIMPs dark matter by means of NaI(Tl) scintillator. To investigate the WIMPs candidate whose cross section is as small as pb, a pure NaI(Tl) crystal was developed by chemical processing and taking care of surroundings. The concentration of U and Th chain was reduced to ppt and ppt, respectively. It should be remarked that the concentration of Pb which was difficult to reduce reached to the high purity as Bq/kg.

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