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We prove Paley-Littlewood decompositions for the scales of fractional powers of -sectorial operators on a Banach space which correspond to Triebel-Lizorkin spaces and the scale of Besov spaces if is the classical Laplace operator on We use the -calculus, spectral multiplier theorems and generalized square functions on Banach spaces and apply our results to Laplace-type operators on manifolds and graphs, Schr"odinger operators and Hermite expansion.We also give variants of these results for bisectorial operators and for generators of groups with a bounded -calculus on strips.

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