A Poor Man's Derivation of Quantum Compass-Heisenberg Interaction: Superexchange Interaction in J-J Coupling Scheme

The exchange interaction between 5d electrons in t${}_{2g}$ orbitals is derived in the J-J coupling scheme which is the appropriate basis in the case of strong spin-orbit interaction. From simple calculations, it is found that ferromagnetic Ising interaction (quantum compass model) occurs due to a selection rule of hybridization between ${\mathrm{\Gamma }}_7$ and ${\mathrm{\Gamma }}_8$ orbitals, while antiferromagnetic Heisenberg interaction appears from hybridization between ${\mathrm{\Gamma }}_7$ orbitals. It is also found that the ferromagnetic Ising interaction becomes small as the spin-orbit interaction increases. Thus, the sign of exchange interaction changes from ferromagnetic Ising to antiferromagnetic Heisenberg interaction as the spin-orbit interaction increases.