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The overarching goal of this paper is to link the notion of sets of finite perimeter (a concept associated with -spaces) and the theory of heat semigroups (a concept related to -spaces) in the setting of metric measure spaces whose measure is doubling and supports a -Poincar'e inequality. We prove a characterization of sets of finite perimeter in terms of a short time behavior of the heat semigroup in such metric spaces. We also give a new characterization of functions in terms of a near-diagonal energy in this general setting.

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