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In the present paper we derive a new Hankel determinant representation for the square of the Vorob’ev-Yablonski polynomial . These polynomials are the major ingredients in the construction of rational solutions to the second Painlev'e equation . As an application of the new identity, we study the zero distribution of as by asymptotically analyzing a certain collection of (pseudo) orthogonal polynomials connected to the aforementioned Hankel determinant. Our approach reproduces recently obtained results in the same context by Buckingham and Miller \cite{BM}, which used the Jimbo-Miwa Lax representation of PII equation and the asymptotical analysis thereof.

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