We present exact analytical solutions for the radial Dunkl-Schrödinger equation (DSE) confined by the Deng-Fan molecular potential. By employing the Pekeris approximation to resolve the centrifugal singularity and applying the parametric Nikiforov-Uvarov method, we derive closed-form expressions for the energy eigenspectrum and the corresponding radial wavefunctions expressed in terms of Jacobi polynomials. Our investigation reveals that the Dunkl reflection parameter fundamentally alters the system’s topology by breaking spatial symmetry and introducing a parity-dependent repulsive force. Numerical analysis demonstrates a monotonic increase in energy eigenvalues with increasing , confirming an effective “hard core” behavior at the origin. The results are shown to be consistent with standard quantum mechanics in the limit . This study establishes the Dunkl formalism as a robust tool for modeling quantum systems characterized by parity-dependent exclusion effects and strong short-range correlations.

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