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We examine quantum phases emerged by double degeneracy of -orbital bands in attractive atomic Fermi gases loaded on a 1D optical lattice. Our numerical simulations by the density-matrix renormalization group predict the emergence of a state with a charge excitation gap, the Haldane insulator phase. A mapping onto an effective spin- model reveals its physical origin. Moreover, we show that population imbalance leads to richer diversity of the quantum phases, including a phase-separated polarized state. Finally, we study the effects of harmonic trap potential in this 1D chain.

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