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We investigate a mixture of ultracold fermionic K atoms and weakly bound LiK dimers on the repulsive side of a heteronuclear atomic Feshbach resonance. By radio-frequency spectroscopy we demonstrate that the normally repulsive atom-dimer interaction is turned into a strong attraction. The phenomenon can be understood as a three-body effect in which two heavy K fermions exchange the light Li atom, leading to attraction in odd partial-wave channels (mainly p-wave). Our observations show that mass imbalance in a fermionic system can profoundly change the character of interactions as compared to the well-established mass-balanced case.

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