We report an observation of the and $B^0 \to J/\psi \eta K^0_S\times 10^{6}$ pairs collected at the resonance with the Belle detector at the KEKB asymmetric-energy collider. We obtain the branching fractions ${\cal B}(B^{\pm}\rightarrow J/\psi\eta K^{\pm})=(1.27\pm 0.11{\rm (stat.)\pm 0.11{\rm (syst.)})}\times10^{-4}{\cal B}(B^0\to J/\psi \eta K^0_S)=(5.22 \pm 0.78 {\rm(stat.)} \pm 0.49{\rm(syst.)})\times10^{-5}$. We search for a new narrow charmonium(-like) state in the mass spectrum and find no significant excess. We set upper limits on the product of branching fractions, , at 3872 MeV where a -odd partner of X(3872) may exist, at and assuming their known mass and width, and over a range from 3.8 to 4.8 GeV. % at a 5 MeV step. The obtained upper limits at 90% confidence level for , and are 3.8$\times 10^{-6}\times 10^{-6}\times 10^{-6}$, respectively.

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