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A combinatorial formula for Pfaffian for the universal enveloping algebra of the affine Kac - Moody algebra of even orthogonal Lie algebra is proved. It allows easily to compute the image of this Segal-Sugawara vector under the Harish-Chandra homomorphism and to deduce formulas for classical Pfaffian of universal enveloping algebra of the even orthogonal Lie algebra.

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