A measurement of production is presented in the invariant-mass region near the pair production threshold, GeV, in final states with two charged leptons and multiple jets. The measurement is based on of proton-proton collision data collected at TeV with the ATLAS detector at the Large Hadron Collider. The data are compared to two models of production: a baseline model including only perturbative QCD predictions for the hard process at approximate next-to-next-to leading order accuracy in the strong coupling, and an extended model that, in addition, incorporates non-relativistic QCD simulations that also include the formation of colour-singlet quasi-bound-states near the threshold. The agreement between the data and the models is quantified via a profile-likelihood fit to the reconstructed distributions, in bins of two angular observables sensitive to spin-correlations in the system. An excess of events is observed over the baseline perturbative QCD prediction, with an observed significance over standard deviations. This excess is consistent with the formation of colour-singlet and spin-singlet -wave quasi-bound states, as predicted by non-relativistic QCD, and corresponds to an observed cross-section of pb.

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