We show that every Hankel operator is unitarily equivalent to a pseudo-differential operator of a special structure acting in the space . As an example, we consider integral operators in the space with kernels where is an arbitrary real polynomial of degree . In this case, is a differential operator of the same order . This allows us to study spectral properties of Hankel operators with such kernels. In particular, we show that the essential spectrum of coincides with the whole axis for odd, and it coincides with the positive half-axis for even. In the latter case we additionally find necessary and sufficient conditions for the positivity of . We also consider Hankel operators whose kernels have a strong singularity at some positive point. We show that spectra of such operators consist of the zero eigenvalue of infinite multiplicity and eigenvalues accumulating to and . We find the asymptotics of these eigenvalues.

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