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We study {0,\alpha}-sets, which are sets of unit vectors of in which any two distinct vectors have angle 0 or \alpha. We investigate some distance-regular graphs that provide new constructions of {0,\alpha}-sets using a method by Godsil and Roy. We prove bounds for the sizes of {0,\alpha}-sets of flat vectors, and characterize all the distance-regular graphs that yield {0,\alpha}-sets meeting the bounds at equality.

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