Block sensitivity (), certificate complexity () and fractional certificate complexity () are three fundamental combinatorial measures of complexity of a boolean function . It has long been known that $bs(f) \leq C^{\ast}(f) \leq C(f) =O(bs(f)^2)$. We provide an infinite family of examples for which grows quadratically in (and also ) giving optimal separations between these measures. Previously the biggest separation known was . We also give a family of examples for which . These examples are obtained by composing boolean functions in various ways. Here the composition of with is obtained by substituting for each variable of a copy of on disjoint sets of variables. To construct and analyse these examples we systematically investigate the behaviour under function composition of these measures and also the sensitivity measure . The measures , and behave nicely under composition: they are submultiplicative (where measure is submultiplicative if ) with equality holding under some fairly general conditions. The measure is qualitatively different: it is not submultiplicative. This qualitative difference was not noticed in the previous literature and we correct some errors that appeared in previous papers. We define the composition limit of a measure at function , to be the limit as grows of , where is the iterated composition of with itself -times. For any function we show that and characterize , and in terms of the largest eigenvalue of a certain set of matrices associated with .

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