Scaling relation for the bond length, mass density, and packing order of water ice

The packing order of molecules and the distance between adjacent oxygen atoms (dOO) in water and ice are most basic yet puzzling. Here we present a scaling solution for this purpose based only on the mass density (gcm-3), (Equation) where dL is the length ({\AA}) of the O:H van der Waals bond and dH the H-O polar-covalent bond projecting on the O—O line. Validated by the measured proton symmetrization of compressed ice, dOO of water and ice, and dOO expansion at water surface, this solution confirms that the fluctuated, tetrahedrally-coordinated structure is unique for water ice.