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Using the meson wave function extracted from non-leptonic decays, we evaluate the short distance contribution of rare decays $B_s\to \ell^+\ell^-\gamma(\ell=e,\mu)$ in the standard model, including all the possible diagrams. We focus on the contribution from four-quark operators which are not taken into account properly in previous researches. We found that the contribution is large, leading to the branching ratio of $B_s\to \ell^+\ell^-\gamma1.7\times 10^{-8}$. The predictions for such processes can be tested in the LHC-b and B factories in near future.

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