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We show how to measure the structural witnesses proposed in [P. Krammer et al., Phys. Rev. Lett. 103, 100502 (2009)] for detecting entanglement in a spin chain using photon scattering. The procedure, moreover, allows one to measure the two-point correlation function of the spin array. This proposal could be performed in existing experimental platforms realizing ion chains in Paul traps or atomic arrays in optical lattices.

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