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We discuss the possibilities of testing the recent claims of a relatively large value of the B --> D’ transition form factor through B0–> D’ pi+ and B- –> D’ pi- decay modes. To estimate the width of the latter we need the decay constant of the radially excited D-meson that we computed in lattice QCD with Nf=2 dynamical flavors and after taking the continuum limit we found f(D’)=117(25) MeV. We also provide an update for the values of the D-meson decay constants obtained by using maximally twisted mass QCD.

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