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This paper studies groups of maximal size acting harmonically on a finite graph. Our main result states that these maximal graph groups are exactly the finite quotients of the modular group of size at least 6. This characterization may be viewed as a discrete analogue of the description of Hurwitz groups as finite quotients of the -triangle group in the context of holomorphic group actions on Riemann surfaces. In fact, as an immediate consequence of our result, every Hurwitz group is a maximal graph group, and the final section of the paper establishes a direct connection between maximal graphs and Hurwitz surfaces via the theory of combinatorial maps.

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