We report an angle-resolved photoemission spectroscopy investigation of the Fermi surface and electronic band structure of BaCoAs. Although its quasi-nesting-free Fermi surface differs drastically from that of its Fe-pnictide cousins, we show that the BaCoAs system can be used as an approximation to the bare unoccupied band structure of the related BaFeCoAs and BaKFeAs compounds. However, our experimental results, in agreement with dynamical mean field theory calculations, indicate that electronic correlations are much less important in BaCoAs than in the ferropnictides. Our findings suggest that this effect is due to the increased filling of the electronic 3 shell in the presence of significant Hund’s exchange coupling.

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