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We develop some sufficient conditions for the stochastic ordering between hitting times, in a fixed state, for two Markov chains. In particular, we focus attention on the so called \emph{skip-free} case. In the analysis of such a case, we develop a special type of coupling. We also compare different types of relations between two, non-necessarily skip-free, Markov chains on the same state space. Such relations have a natural role in establishing the usual and the asymptotic stochastic ordering between the probability distributions of hitting times. Finally, we present some discussions and examples related with words’ occurrences.

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