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We establish an exact duality between the extended thermodynamics of five-dimensional charged Gauss-Bonnet AdS black holes and the thermodynamic framework of the dual boundary conformal field theory (CFT). The thermodynamics of the dual CFT involves two central charges originating from the trace anomaly. We demonstrate a precise correspondence between the extended first laws on the bulk and boundary sides. Moreover, the topological charges of the CFT thermodynamics, associated with the phase transition and critical point, coincide with those of the corresponding bulk black hole.

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