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We report the measurement of the branching fraction, the polarization, and the parameters of the time-dependent CP violation in B0 -> D*+ D*- decays using a data sample of 772 million BB pairs, collected at the Y(4S) resonance with the Belle detector at the KEKB asymmetric-energy e+e- collider. We obtain a branching fraction of B = (7.82 ± 0.38 ± 0.63) x10^{-4}, a CP-odd fraction of R_\perp = 0.138 ± 0.024 ± 0.006 and, additionally, a fraction of the longitudinal component in the transversity base of R_0 = 0.624 ± 0.029 ± 0.011. The measured values of the parameters of the CP violation are S_{D*+ D*-} = -0.79 ± 0.13 ± 0.03 and A_{D*+ D*-} = 0.15 ± 0.08 ± 0.04.

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