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We characterize the Mott insulator and Luther-Emery phases of the 1D Hubbard model through correlators that measure the parity of spin and charge strings along the chain. These non-local quantities order in the corresponding gapped phases and vanish at the critical point . The Mott insulator consists of bound doublon-holon pairs, which in the Luther-Emery phase turn into electron pairs with opposite spins, both unbinding at . The behavior of the parity correlators can be captured by an effective free spinless fermion model.

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