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In this work we extend the theory of Stieltjes systems beyond the monotone case, establishing new chain rules, generalized versions of the Fundamental Theorem of Calculus, compactness tools for Peano-type results, and a -exponential for explicit linear solutions. Continuity notions relative to vector-valued derivators further allow us to study everywhere differentiable solutions. As an application, we model thermal stress effects on solar panels and battery health, highlighting the practical value of non-monotone derivators.

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