As and La NMR results of LaFeAs(OF) (=0, 0.025, and 0.04) were reported. Upon F-doping, the tetragonal-to-orthorhombic structural phase transition temperature , antiferromagnetic transition temperature and internal magnetic field are gradually reduced for . However, at , is abruptly suppressed to be 30 K along with a tiny , which is distinct from the continuous disappearance of the ordered phases in the Ba122 systems of Ba(Fe,Co)As and BaFe(As,P). The anisotropy of the spin-lattice relaxation rate , $(T_1)^{-1}{H\parallel ab}/(T_1)^{-1}{H\parallel c}x = 0\sim 1.5$), but increases abruptly below due to the enhancement of by the slowing down of magnetic fluctuations. This indicates that the tetragonal-to-orthorhombic structural distortion enhances the anisotropy in the spin space via magnetoelastic coupling and/or spin-orbit interaction.

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