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We derive the exact critical line of the O() loop model on the martini lattice as a function of the loop weight .A finite-size scaling analysis based on transfer matrix calculations is also performed.The numerical results coincide with the theoretical predictions with an accuracy up to 9 decimal places. In the limit , this gives the exact connective constant of self-avoiding walks on the martini lattice. Using similar numerical methods, we also study the O() loop model on the 3-12 lattice. We obtain similarly precise agreement with the exact critical points given by Batchelor [J. Stat. Phys. 92, 1203 (1998)].

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